Did he get into something, or is this stuff "growing" there? If it is something he got into, don't scrape or peel it off-- instead, use a cotton ball or gauze pad soaked with a bit of rubbing alcohol (alcohol is a solvent) to rub it off. Don't use peroxide, because hydrogen peroxide will discolor his nails and the fur in his paws. However, alcohol can dry his pads, causing them to chap, so when you get done you might want to rub a small amount of moisturizer into the pads so they don't dry out and crack.
If the gunk seems to be "growing" there, then you need to get him in to see the vet, since it could be some sort of fungal infection.
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